Now the basic of this concept is from very fundamental quantum chemistry formulation but I dont think you need to know that now It is. Electron configuration for which there is an obsolete system of categorizing spectral lines as s harp p rincipal d iffuse and f undamental.
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By SPDF configuration he meant orbital configuration.

Spdf. Space Physics Data Facility SPDF is the NASA active and permanent archive for non-solar heliophysics data solar data at SDAC per the NASA Heliophysics Science Data Management. Spdf or SPDF may refer to.
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